Ever since the statistical interpretation of entropy became popular, more than a century ago, students have been taught that entropy tends to favor a state of greater disorder over a more ordered state, and that the inevitable increase in the entropy, or disorder, of the universe provides a direction for time.
A typical example is found in Richard Feynman's discussion of irreversibility [The Feynman Lectures on Physics,Vol. I, 46-7], where he uses italics to emphasize:
"It is the change from an ordered arrangement to a disordered arrangement which is the source of the irreversibility."
The truth of this sort of statement hinges on a
proper understanding of what is meant by
"a
disordered arrangement," a meaning that may not be obvious to a naïve
reader and is not always clarified (Feynman does address it
several paragraphs later, see answer below).
One approach to a proper understanding of
order and disorder is to consider a scientific parlor trick
(one that is often analogized to spin- or optical-echo
experiments). The demonstration involves
Couette
flow of a viscous liquid in the
space between two coaxial cylinders. On the right is the first frame from a
movie showing the spreading of a yellow dye in a viscous
liquid (shown blue in the cross section on the
left). The liquid is held between a
stationary interior rod and a rotatable glass
tube. In the movie the outside tube is rotated
to the left by three complete turns, 3 x 360° =
1080° (note black reference line)
and then rotated back again.
At first this seems quite surprising.
Because the liquid appears uniformly yellow after rotation, it is
natural to assume that the dye has been randomly and uniformly
mixed throughout the liquid. "Unmixing" should be impossible, as
is pointed out by the 13-year-old prodigy Thomasina to her tutor
Septimus in Tom Stoppard's 1993 play "Arcadia":
Cross Section
(The watch proves that there has been no software
hankypanky.)
THOMASINA: When you stir your rice pudding, Septimus, the spoonful of jam spreads itself round making red trails like the picture of a meteor in my astronomical atlas. But if you stir backward, the jam will not come together again. Indeed, the pudding does not notice and continues to turn pink just as before. Do you think this is odd?
SEPTIMUS: No.
THOMASINA: Well, I do. You cannot stir things apart.
SEPTIMUS: No more you can, time must needs run backward, and since it will not, we must stir our way onward mixing as we go, disorder out of disorder into disorder until pink is complete, unchanging and unchangeable, and we are done with it for ever.
In fact the flow of the viscous liquid is, to a first approximation, laminar and without turbulence, inertial flow, or
diffusion. The amount of angular displacement of any bit of
liquid depends only on its distance from the axis of the
cylinders. The liquid has been cleanly sheared. Bits of liquid next to the rotating outer
cylinder rotate with it by 1080°, while those next to
the stationary inner cylinder do not rotate at all. After
three cycles of rotation the dye forms a thin sheet wound
three times around the cylinder axis (as shown by the red
line in the cross section at the left). Viewed from the
side, the dye appears to be evenly distributed, because from that perspective we
cannot perceive the pattern. Reversing the rotation "unwinds" the
spiral sheet back into the original line.
What fooled us was the appearance of randomness after
1080° rotation. The dye was just as ordered after rotation as
it was before, but in a less easily perceived way.
Cross Section after 1080° rotation
[Of course this kind of non-turbulent
"mixing" does accelerate true dissolution by shortening
the distances that need to be covered by randomizing
diffusion, but diffusion in a liquid as viscous as corn
syrup is very slow.]
This Couette flow demonstration makes us
cautious about supposing that an arrangement is random or
"disordered" just by the look of it. What appears to be
disordered may truly be ordered but in a very complicated
way. In fact any arrangement at all might
be considered "ordered" by someone. Compare the two sets of 52 dots in the
frames to the right. Most individuals would think of the
second arrangement as rather disordered, but you can
click
here to see that the second is also highly
ordered.
Of course one can arbitrarily define some
quantitative measure of the randomness of a distribution
(e.g. the fractal dimension), but different individuals
could choose different measures.
If any arrangement may be considered ordered - if order is in the eye of the beholder - the concept of "a disordered arrangement" is an oxymoron and dangerous to use in a fundamental theory.
"It is the change from an ordered
arrangement to a disordered arrangement |
|
Reversible Couette Flow as a model of spin and optical echos is discussed by R. G. Brewer and E. L. Hahn, in "Atomic Memory", Scientific American, 251, No. 6, pp. 50-57 (December, 1984) [thanks to Victor Batista for this reference]
For a more physical description of the Couette unmixing experiment see John P. Heller "An Unmixing Demonstration," American Journal of Physics, 28, 348-353 (1960).
Tom Stoppard, "Arcadia", Faber and Faber, Boston, 1993. Act I, Scene 1. [Thanks to J. D. Dunitz for pointing out this passage.]
Dinosaur connect-the-dots from http://www.lizardpoint.com/fun/java/dinodots/dino1.html
|
|